Bao Fang, Li Zhiming, Zhang Meizheng, Wang Rucheng. Application of laser Raman spectrum in organic maceral studies[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2012, 34(1): 104-108. doi: 10.11781/sysydz201201104
Citation: Bao Fang, Li Zhiming, Zhang Meizheng, Wang Rucheng. Application of laser Raman spectrum in organic maceral studies[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2012, 34(1): 104-108. doi: 10.11781/sysydz201201104

Application of laser Raman spectrum in organic maceral studies

doi: 10.11781/sysydz201201104
  • Received Date: 2011-05-17
  • Rev Recd Date: 2011-12-06
  • Publish Date: 2012-01-28
  • The former tests of coal maceral were usually carried out manually and were influenced obviously by manual elements.Laser Raman spectrum deals with the order and deficiency of carbon matter structure and analyzes the features of organic maceral from the aspect of molecular structure.In this paper,the features and classifications of laser Raman spectrum of three macerals(vitrinite,semifusinite and fusinite)in source rocks have been discussed.The comparisons of laser Raman spectrum parameters between different macerals have been made and the structures of different macerals have been analyzed.In this way,we intend to find a new way to distinguish different macerals quickly and precisely using laser Raman spectrum.It has been found out that,in certain maturity range,obvious difference exists between D1 peak and G peak half-width among different organic macerals.This might be used as a new standard to distinguish different organic macerals.Laser Raman spectrum identifies the macerals in coals and rock samples quickly and effectively.It is an effective method in maceral analyses.

     

  • loading
  • [1]
    程光煦.拉曼布里渊散射:原理及应用[M].北京:科学出版社,2001.
    [2]
    杨士娟,李瑗.拉曼散射光谱及其应用[J].高教装备,2006(8):56-57.
    [3]
    李美芬,曾凡桂,齐福辉,等.不同煤级煤的Raman谱特征及与XRD结构参数的关系[J].光谱学与光谱分析,2009,29(9):2446-2449.
    [4]
    李东风,王浩静,王心葵.PAN基碳纤维在石墨化过程中的拉曼光谱[J].光谱学与光谱分析,2007,27(11):2249-2253.
    [5]
    Potgieter-Vermaak S,Maledi N,Wagner N,et al.Raman spectroscopy for the analysis of coal:a review[J].J Raman Spectrosc,2011,42:123-129.
    [6]
    Beyssac O,Goffe B,Petitet J P,et al.On the characterization of disordered and heterogeneous carbonaceous materials by Raman spectroscopy[J].Spectrochimica Acta Part A,2003,59:2267-2276.
    [7]
    谢克昌.煤的结构与反应性[M].北京:科学出版社,2002.
    [8]
    何谋春,吕新彪,刘艳荣,激光拉曼光谱在油气勘探中的应用研究初探[J].光谱学与光谱分析,2004,24(11):1363-1366.
    [9]
    汪洋,胡凯.应用激光喇曼光谱特征参数反映有机碳质的成熟度[J].矿物岩石,2002,22(3):57-60.
    [10]
    Quirico E,Rouzaud J N,Bonal L,et al.Maturation grade of coals as revealed by Raman spectroscopy:Progress and problems[J].Spectrochimica Acta Part A,2005,61:2368-2377.
    [11]
    Jehlicka J,Edwards H G.M.Raman spectroscopy as a tool for the non-destructive identification of organic minerals in the geological record[J].Organic Geochemistry,2008,39:371-386.
    [12]
    Beyssac O,Goffe B,Chopin C,et al.Raman spectra of carbonaceous material in metasediments:a new geothermometer.[J].JMetamorphic Geol,2002,20:859-871.
    [13]
    冯有利,郑辙,郭延军.碳化树木的微结构特征研究[J].北京大学学报,2003,39(5):727-731.
    [14]
    Sadezky A,Muckenhuber H,Grothe H,et al.Raman microspectroscopy of soot and related carbonaceous materials:Spectral analysis and structural information[J].Carbon,2005,43:1731-1742.
    [15]
    Ferrari A C,Robertson J.Interpretation of Raman spectra of disordered and amorphous carbon[J].Phys Rev B,2000,61(20):14095-14107.
    [16]
    Dresselhaus M S,Dresselhaus G.Topics in applied physics[M].Berlin:Springer-Verlag,1982:3-57.
    [17]
    Jawhari T,Roid A,Casado J.Raman spectroscopic characterization of some commercially available carbon black materials[J].Carbon,1995,33:1561-1565.
    [18]
    Kudryavtsev A B,Schopf J W,Agresti D G,et al.In situ laserRaman imagery of Precambrian microscopic fossils[J].Proc Natl Acad Sci USA,2001,98:823.
    [19]
    Tuinstra F,Koenig J L.Raman spectrum of graphite[J].J Chem Phys,1970,53:1126-1130.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (4182) PDF downloads(1191) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return