Determination of halogenated hydrocarbons in outlet fluid for shale oil and gas reservoir fracturing by purge-and-trap and GC-MS

Guo Wei; Huang Chunhua; Zhao Xionghu; Zhang Xiaotao; Shen Bin; Wang Shuangqing; Sun Weilin

doi:10.11781/sysydz201706865

Volume 39 Issue 6

Turn off MathJax

Article Contents

Abstract

References

Article Navigation > PETROLEUM GEOLOGY & EXPERIMENT > 2017 > 39(6): 865-872

Guo Wei, Huang Chunhua, Zhao Xionghu, Zhang Xiaotao, Shen Bin, Wang Shuangqing, Sun Weilin. Determination of halogenated hydrocarbons in outlet fluid for shale oil and gas reservoir fracturing by purge-and-trap and GC-MS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2017, 39(6): 865-872. doi: 10.11781/sysydz201706865

Citation:

Guo Wei, Huang Chunhua, Zhao Xionghu, Zhang Xiaotao, Shen Bin, Wang Shuangqing, Sun Weilin. Determination of halogenated hydrocarbons in outlet fluid for shale oil and gas reservoir fracturing by purge-and-trap and GC-MS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2017, 39(6): 865-872. doi: 10.11781/sysydz201706865

Citation:

Guo Wei, Huang Chunhua, Zhao Xionghu, Zhang Xiaotao, Shen Bin, Wang Shuangqing, Sun Weilin. Determination of halogenated hydrocarbons in outlet fluid for shale oil and gas reservoir fracturing by purge-and-trap and GC-MS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2017, 39(6): 865-872. doi: 10.11781/sysydz201706865

PDF( 967 KB)

Determination of halogenated hydrocarbons in outlet fluid for shale oil and gas reservoir fracturing by purge-and-trap and GC-MS

doi: 10.11781/sysydz201706865

1.
Oil & Gas Geochemistry Department, National Research Center for Geoanalysis, Beijing 100037, China
2. Drilling Fluid Laboratory, China University of Petroleum(Beijing), Beijing 102249, China

Received Date: 2017-08-07
Rev Recd Date: 2017-09-14
Publish Date: 2017-11-28

Abstract

Abstract

In shale oil and gas exploration, chemical tracer technology is effectively applied to the evaluation of fracturing technology. The precondition for the application of this technology is the establishment of corresponding analysis method. The authors selected 21 kinds of halogenated hydrocarbons as tracer, with stable chemistry character and low stratigraphic background values. And a high sensitivity detection method for the tracer by purge-and-trap and gas chromatography mass spectrometry (GC-MS) was developed. The conditions of purge-and-trap and GC-MS were optimized and the optimum conditions were obtained. The results showed that the detection limits were 0.027-0.162 μg/L. The average recoveries were 74.16%-121.9% with a precision lower than 12.79% (RSD, n=7). The established method is simple and fast, hence is applicable for the determination of tracer in fracturing outlet fluid samples after reservoir reconstruction.
- halogenated hydrocarbons,
- chemical tracer,
- purge-and-trap and GC-MS,
- shale oil and gas

FullText(HTML)

References(22)

References

[1]	Catlett R D,Spencer J D,Lolon E,et al.Evaluation of two horizontal wells in the eagle ford using oil-based chemical tracer technology to optimize stimulation design[C]//SPE Hydraulic Fracturing Technology Conference.Texas,USA:Society of Petro-leum Engineers,2013.
[2]	Zhang K S,Tang M R,Yong S S,et al.Evaluation of stage contribution and interwell connectivity during initial flowback and oil production in a tight oil horizontal stimulation using tracer technology[C]//SPE Asia Pacific Hydraulic Fracturing Conference.Beijing,China:Society of Petroleum Engineers,2016.
[3]	刘同敬,姜宝益,刘睿,等.多孔介质中示踪剂微观可视化实验研究[J].断块油气田,2013,20(4):530-534. Liu Tongjing,Jiang Baoyi,Liu Rui,et al.Experimental study on microcosmic visualization of tracer in porous medium[J].Fault-Block Oil and Gas Field,2013,20(4):530-534.
[4]	翟亮.基于流线的示踪剂技术研究薄层底水油藏开发规律[J].特种油气藏,2011,18(1):79-82. Zhai Liang.Study on the development rule of thin reservoirs with bottom water by stream line-based tracer technology[J].Special Oil & Gas Reservoirs, 2011,18(1):79-82.
[5]	巫波,刘遥,荣元帅,等.碳酸盐岩油藏缝洞差异连通及水淹特征研究[J].特种油气藏,2015,22(1):131-133. Wu Bo,Liu Yao,Rong Yuanshuai,et al.Fracture-cavern different connections and water-out in carbonate reservoir[J].Special Oil & Gas Reservoirs,2015,22(1):131-133.
[6]	于瑞香,张泰山,周伟生.油田示踪剂技术[J].工业水处理,2007,27(8):12-15. Yu Ruixiang,Zhang Taishan,Zhou Weisheng.Technique in oil field tracer[J].Industrial Water Treatment,2007,27(8):12-15.
[7]	Williams R L,McCarthy J T.Using multiple radioactive tracers to optimize stimulation designs[C]//SPE California Regional Meeting.Ventura:Society of Petroleum Engineers,1987.
[8]	刘佳文,陈学元,李武胜.同位素示踪剂井间监测技术在狮子沟油田N1油藏的应用[J].同位素,2008,21(1):54-57. Liu Jiawen,Chen Xueyuan,Li Wusheng.Application of isotope tracer interwell monitoring technique in N1 of Shizigou oilfield[J].Journal of Isotopes,2008,21(1):54-57.
[9]	马云,池晓明,黄东安.用于多段压裂的微量物质示踪剂与压裂液的配伍性研究[J].精细石油化工,2016,33(2):50-53. Ma Yun,Chi Xiaoming,Huang Dong'an.Compatibility for trace substances of multi-stage fracturing and fracturing fluid[J].Speciality Petrochemicals,2016,33(2):50-53.
[10]	易飞,江涛,陈维余,等.一种油田用速溶型微量元素示踪剂及制备方法:CN102296947A[P].2011-05-30. Yi Fei,Jiang Tao,Chen Weiyu,et al.A instant rare earth element tracer in oilfield and its preparation method:CN102296947A[P].2011-05-30.
[11]	Kuchuk F J,Lenn C,Hook P,et al.Performance evaluation of horizontal wells[C]//SPE Asia Pacific Conference on Integrated Modelling for Asset Management.Kuala Lumpur,Malaysia:Society of Petroleum Engineers,1998.
[12]	Hewitt P,Spencer J D,Croud V B.Method of tracing flow of hydrocarbon from a subterranean reservoir:US Patent 8640773[P].2016-03-15.
[13]	黄毅,李国傲,饶竹,等.城市环境地下水调查样品中挥发性有机物测定[J].质谱学报,2012,33(5):301-307. Huang Yi,Li Guoao,Rao Zhu,et al.Determination of volatile organic compounds in city groundwater by GC/MS with purge and trap sampling[J].Journal of Chinese Mass Spectrometry Society,2012,33(5):301-307.
[14]	贾静,刘艳.吹扫捕集气相色谱-质谱法测定土壤中54种挥发性有机物[J].分析试验室,2011,30(10):92-97. Jia Jing,Liu Yan.Analysis of 54 volatile organic compounds in soil by using purge and trap-gas chromatography/mass spectrometry[J].Chinese Journal of Analysis Laboratory,2011,30(10):92-97.
[15]	No C C A S.Method 5030C Purge and trap for aqueous samples.Cincinnati,Ohio:U.S. Envnmental Protection Agency,2003.
[16]	Techniquea A P.Method 8260B Volatile organic compounds by gas chromatography/mass spectrometry(GC/MS)[R].Cincinnati,Ohio:U.S. Envnmental Protection Agency,1996.
[17]	Eichelberger J W,Budde-Revision W L,Munch J W,et al.Method 524.2 measurement of purgeable organic compounds in water by capillary column gas chromatography/mass spectrometry[R].Cincinnati,Ohio:Environmental monitoring systems laboratory office of research and development,US EPA,1989.
[18]	苟德国,束华勇.吹扫捕集-气相色谱同步测定苯系物和卤代烃[J].广州化工,2016,44(7):134-136. Gou Deguo,Shu Huayong.Simultaneous determination of BTEX and VHH by purge-and-trap gas chromatoraphy[J].Guangzhou Chemical Industry and Technology,2016,44(7):134-136.
[19]	卢明伟.吹扫捕集气相色谱法测定水中苯系物[J].化学分析计量,2008,17(2):25-27. Lu Mingwei.Determination of benzene series in water by purge and trap with gas chromatography[J].Chemical Analysis and Meterage,2008,17(2):25-27.
[20]	张艳萍,肖兵,丁国清,等.吹扫捕集气相色谱法测定饮用水中15种挥发性卤代烃的方法研究[J].中国卫生检验杂志,2010,20(9):2187-2188. Zhang Yanping,Xiao Bing,Ding Guoqing,et al.Determination of 15 volatile halogenated hydrocarbons in drinking water by purge-and-trap gas chromatography[J].Chinses Journal of Health Laboratory Technology,2010,20(9):2187-2188.
[21]	刘盛田.吹扫捕集气相色谱法测定饮用水中多种卤代烃[J].中国卫生检验杂志,2010,20(10):2450-2452. Liu Shengtian.Determination of variety of halogenated hydrocarbons in drinking water by purge and trap gas chromatography[J].Chinese Journal of Health Laboratory Technology,2010,20(10):2450-2452.
[22]	Eichelberger J W,Behymer T D,Budde W L.Determination of organic compounds in Drinking water by liquid-solid extraction and capillary column gas chromatography/mass spectrometry[R]. Cincinnati,Ohio:Environmental Monitoring Systems Laboratory, US EPA,1988.

Relative Articles

[1]	GUO Xusheng, SHEN Baojian, LI Zhiming, WAN Chengxiang, LI Chuxiong, LI Qianwen. Discussion on the uniformity of shale oil and gas in China[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(5): 889-905. doi: 10.11781/sysydz202405889
[2]	CHEN Chao, LIU Xiaojing, LIU Miaomiao, CHEN Huixia, XIE Jiatong. Oil and gas exploration potential of continental shale of Lianggaoshan Formation of Middle Jurassic in Qijiang area of southeastern Sichuan[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(5): 1015-1027. doi: 10.11781/sysydz2024051015
[3]	JIA Mengyao, BAO Yunjie, LI Zhiming, SHEN Baojian, CAO Tingting, LIU Peng, YANG Zhenheng, LU Longfei, LI Maowen. Preliminary application and prospect of well site determination technology of gaseous hydrocarbon in continental shale cores[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(1): 183-190. doi: 10.11781/sysydz202401183
[4]	WEI Caiyun, MA Xingzhi, HU Guoyi, XU Huaixian, LIU Shaobo, WEI Jinhong, WENG Na, LÜ Yue. Evaluation of laboratory comparison results of GC and GC-MS in petroleum geology industry[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2023, 45(3): 528-536. doi: 10.11781/sysydz202303528
[5]	WU Fenting, XIE Xiaomin, XU Yaohui, LIN Jingwen, ZHANG Lei, XU Jin, MA Zhongliang. A comparative study on the geochemical characteristics of expelled and retained oil from hydrocarbon generation simulation of Australian Tasmanian oil shale Ⅱ: molecular geochemical characteristics[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2022, 44(2): 314-323. doi: 10.11781/sysydz202202314
[6]	SHEN Baojian, PAN Anyang, ZHANG Jun, LU Longfei, QIAN Menhui, LU Shuanglong, DU Mingliang. Evaluating the connectivity of shale gas wells by new rare element tracers[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2021, 43(5): 855-861. doi: 10.11781/sysydz202105855
[7]	ZHU Tong. Main controlling factors and types of continental shale oil and gas enrichment in Sichuan Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2020, 42(3): 345-354. doi: 10.11781/sysydz202003345
[8]	CAO Tingting, YAO Wei, LI Zhiming, LI Zheng, LI Maowen. Geochemical characteristics of lacustrine shale and enrichment mechanism of organic matter in Zhanhua Sag, Bohai Bay Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2020, 42(4): 558-564. doi: 10.11781/sysydz202004558
[9]	HUANG Zhenkai, LI Maowen, ZHENG Lunju, TAO Guoliang, LI Zhiming, JIANG Qigui, QIAN Menhui, CAO Tingting, LI Shuangjian, WO Yujin, SUN Dongsheng. Pore development in lacustrine source rock evolution: interpretation based on geological samples and simulation experiments: interpretation based on geological samples and simulation experiments[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2020, 42(4): 639-645. doi: 10.11781/sysydz202004639
[10]	LIU Guoheng, ZHAI Gangyi, ZOU Caineng, HUANG Zhilong, XIA Xianghua, SHI Dishi, ZHOU Zhi, CHEN Rong, ZHANG Cong, YU Shufang. Silicon sources and hydrocarbon accumulation in shale, Triassic Yanchang Formation, Ordos Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2019, 41(1): 45-55. doi: 10.11781/sysydz201901045
[11]	MA Haiyang, XIA Zunyi, WEN Qingzhi, ZHANG Pengyu. Micro-pore characteristics of shale in Zhanhua Sag, Bohai Bay Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2019, 41(1): 149-156. doi: 10.11781/sysydz201901149
[12]	WANG Wei, HUANG Dong, YI Haiyong, ZHAO Rongrong, CEN Yongjing, LI Yucong. Stratigraphic division and geochemical characteristics of freshwater lacustrine shale: a case study of Jurassic Da'anzhai Section, Sichuan Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2019, 41(5): 724-730. doi: 10.11781/sysydz201905724
[13]	ZHAO Yue, CAI Jingong, XIE Aobo, DONG Zhe, ZHOU Qisheng, LEI Tianzhu, YANG Yan. Geochemical investigation of organic matter of various occurrences released via sequential treatments of two argillaceous source rock samples from fresh and saline lacustrine environments[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2018, 40(5): 705-715. doi: 10.11781/sysydz201805705
[14]	Wang Baohua, Lu Jianlin, Li Hao, Song Zhenxiang, Zuo Zongxin. Recovery method for total porosity of shale based on porosity origin: A case study of the lower part of the third member of Shahejie Formation in the Dongying Sag, Bohai Bay Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2017, 39(5): 724-728. doi: 10.11781/sysydz201705724
[15]	Xu Xuhui, Zheng Lunju, Ma Zhongliang. Organic matter occurrence and hydrocarbon generation in shale[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2016, 38(4): 423-428. doi: 10.11781/sysydz201604423
[16]	Jiang Qigui, Shen Baojian, Yang Yunfeng, Li Zhiming, Ma Yuanyuan, Qian Menhui. Kinetic analysis of hydrocarbon generation components in shales from the Bonan sub-Sag and its significance for hydrocarbon exploration[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2016, 38(2): 231-239. doi: 10.11781/sysydz201602231
[17]	Liu Guoheng, Huang Zhilong, Jiang Zhenxue, Chen Jianfa, Chen Feiran, Xing Jinyan. Effect of liquid hydrocarbons on gas adsorption in alacustrine shale: A case study of the Yanchang Formation, Ordos Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2015, 37(5): 648-653. doi: 10.11781/sysydz201505648
[18]	Liu Yanli, Xu Xianghua. Petroleum distribution rules and controlling factor analysis of Gulf of Mexico Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2014, 36(2): 200-205. doi: 10.11781/sysydz201402200
[19]	Zhou Dehua, Jiao Fangzheng, Guo Xusheng, Guo Tonglou, Wei Zhihong. Geologic analysis of Middle-Lower Jurassic shale reservoirs in Yuanba area, northeastern Sichuan Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2013, 35(6): 596-600. doi: 10.11781/sysydz201306596

Supplements(0)

Cited By

Cited by

Periodical cited type(4)

1.	黄嘉林，刘德华，商玉锋. 页岩储层压裂体积规模监测方法研究进展. 辽宁化工. 2022(05): 662-666 .
2.	李博文，徐静，李伯平，闫峻. 气相色谱法同时测定10种卤代烃石油示踪剂的方法研究. 世界核地质科学. 2022(04): 757-765 .
3.	孙翰文，费繁旭，高阳，喻高明，辛显康. 吉木萨尔陆相页岩水平井压裂后产量影响因素分析. 特种油气藏. 2020(02): 108-114 .
4.	袁琴，隋明炜，王艺衡，敖科. 混合水用水相痕量示踪剂室内评价及应用. 当代化工. 2020(11): 2491-2494 .

Other cited types(1)

Proportional views

Proportional views

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Citation

XML

PDF-CN

Article Metrics

Article views (1310) PDF downloads(321)