ZHANG Min, HE Yu, CHEN Zulin, GONG Jianming. Analysis method and geological significance of C5-C7 light hydrocarbons in natural gas hydrate in permafrost, Qilian Mountain[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2018, 40(3): 418-423. doi: 10.11781/sysydz201803418
Citation: ZHANG Min, HE Yu, CHEN Zulin, GONG Jianming. Analysis method and geological significance of C5-C7 light hydrocarbons in natural gas hydrate in permafrost, Qilian Mountain[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2018, 40(3): 418-423. doi: 10.11781/sysydz201803418

Analysis method and geological significance of C5-C7 light hydrocarbons in natural gas hydrate in permafrost, Qilian Mountain

doi: 10.11781/sysydz201803418
  • Received Date: 2017-09-08
  • Rev Recd Date: 2018-03-20
  • Publish Date: 2018-05-28
  • A sample introduction device of vacuum thermal desorption, cold on-column and zero-pressure was built for the identification of C5-C7 light hydrocarbons in gas hydrate. On the basis of previous Kováts index research, 27 compounds of C5-C7 light hydrocarbons were identified, which provided a foundation for the geochemical study on light hydrocarbons in gas hydrate in the Juhugeng mining area, Muli coal field, Qilian Mountain. Two genetic types of gas hydrate in the Muli permafrost were divided into three types, including oil-type, coal-type and mixed-type gas based on the methylcyclohexane index. The mixed-type gas predominates in the Muli permafrost, while the other two types are in the minority.

     

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  • [1]
    SCHAEFER R G,WEINER B,LEYTHAEUSER D.Determination of sub-nanogram per gram quantities of light hydrocarbons (C2-C9) in rock samples by hydrogen stripping in the flow system of a capillary gas chromatograph[J].Analytical Chemistry,1978,50(13):1848-1854.
    [2]
    武杰,陆婉珍.C4~C10烃类在OV-101柱上的保留指数[J].色谱,1984,1(1):11-17. WU Jie,LU Wanzhen.The retention index of C4-C10 hydrocarbon in OV101 column[J].Chinese Journal of Chromatography,1984,1(1):11-17.
    [3]
    詹智玉.岩石与天然气中C1-C9烃类分析方法的研究[J].石油实验地质,1990,12(3):326-332. ZHAN Zhiyu.Study of an analytical method for C1-C9 hydrocarbons in rocks and natural gas[J].Experimental Petroleum Geo-logy,1990,12(3):326-332.
    [4]
    朱俊章,王培荣.原油中nC4-nC14馏分峰的色谱鉴定及地质应用初探[J].色谱,1994,12(5):336-341. ZHU Junzhang,WANG Peirong.The identification of nC4-nC14 fraction in crude oil and its preliminary geological application[J].Chinese Journal of Chromatography,1994,12(5):336-341.
    [5]
    陆诗文,郭宗伟,李宝艳,等.轻烃分析评价储层含油性技术在文中油田的应用[J].化学工程与装备,2012,(12):116-118. LU Shiwen,GUO Zongwei,LI Baoyan,et al.Light hydrocarbon analysis and evaluation of reservoir oil-bearing technology Wenzhong oilfield[J].Chemical Engineering & Equipment,2012,(12):116-118.
    [6]
    李继文,姜丽燕,刘俊彦,等.C5-C7烃类组分在Al2O3毛细管色谱柱上的分离及应用[J].色谱,2015,33(9):1009-1014. LI Jiwen,JIANG Liyan,LIU Junyan,et al.Separation of C5-C7 hydrocarbon components on Al2O3 capillary column and its application[J].Chinese Journal of Chromatography,2015,33(9):1009-1014.
    [7]
    THOMPSON K F M.Light hydrocarbons in subsurface sediments[J].Geochimica et Cosmochimica Acta,1979,43(5):657-672.
    [8]
    MANGO F D.The light hydrocarbons in petroleum:A critical review[J].Organic Geochemistry,1997,26(7/8):417-440.
    [9]
    ODDEN W.A study of natural and artificially generated light hydrocarbons (C4-C13) in source rocks and petroleum fluids from offshore Mid-Norway and the southernmost Norwegian and Danish sectors[J].Marine and Petroleum Geology,1999,16(8):747-770.
    [10]
    THOMPSON K F M.Classification and thermal history of petroleum based on light hydrocarbons[J].Geochimica et Cosmochimica Acta,1983,47(2):303-316.
    [11]
    林壬子.轻烃技术在油气勘探中的应用[M].武汉:中国地质大学出版社,1992. LIN Renzi.Light hydrocarbons techniques & it's application in oil & gas exploration[M].Wuhan:China Geological University Press,1992.
    [12]
    王培荣.烃源岩与原油中轻馏分烃测定及其地球化学应用[M].北京:石油工业出版社,2011. WANG Peirong.The determination of hydrocarbon source rocks and petroleum and their geochemical applications[M].Beijing:Petroleum Industry Press,2011.
    [13]
    SLOAN E D Jr.Clathrate hydrates of natural gases[M].New York:Marcel Dekker,1989:641.
    [14]
    KVENVOLDEN K A.Methane hydrate:A major reservoir of carbon in the shallow geosphere[J].Chemical Geology,1988,7(1/3):41-51.
    [15]
    SLOAN E D.Natural gas hydrate phase equilibria and kinetics:Understanding the state-of-the-art[J].Oil & Gas Science and Technology,1990,45(2):245-266.
    [16]
    MAKOGON Y F,HOLDITCH S A,MAKOGON T Y.Natural gas-hydrates:A potential energy source for the 21st century[J].Journal of Petroleum Science and Engineering,2007,56(1/3):14-31.
    [17]
    WANG Pingkang,HUANG Xia,PANG Shouji,et al.Geochemical dynamics of the gas hydrate system in the Qilian Mountain Permafrost,Qinghai,Northwest China[J].Marine and Petroleum Geology,2015,59:72-90.
    [18]
    STOTLER R L,FRAPE S K,AHONEN L,et al.Origin and stability of a permafrost methane hydrate occurrence in the Canadian Shield[J].Earth and Planetary Science Letters,2010,296(3/4):384-394.
    [19]
    SUN Zhongjun,YANG Zhibin,MEI Hai,et al.Geochemical characteristics of the shallow soil above the Muli gas hydrate reservoir in the permafrost region of the Qilian Mountains,China[J].Journal of Geochemical Exploration,2014,139:160-169.
    [20]
    COLLETT T S,LEE M W,AGENA W F,et al.Permafrost-associated natural gas hydrate occurrences on the Alaska North Slope[J].Marine and Petroleum Geology,2011,28(2):279-294.
    [21]
    LU Zhengquan,ZHU Youhai,LIU Hui,et al.Gas source for gas hydrate and its significance in the Qilian Mountain permafrost,Qinghai[J].Marine and Petroleum Geology,2013,43:341-348.
    [22]
    LU Zhengquan,ZHU Youhai,ZHANG Yongqin,et al.Gas hydrate occurrences in the Qilian Mountain permafrost,Qinghai Province,China[J].Cold Regions Science and Technology,2011,66(2/3):93-104.
    [23]
    王佟,刘天绩,邵龙义等.青海木里煤田天然气水合物特征与成因[J].煤田地质与勘探,2009,37(6):26-30. WANG Tong,LIU Tianji,SHAO Longyi,et al.Characteristics and origins of the gas hydrates in the Muli coalfield of Qinghai[J].Coal Geology & Exploration,2009,37(6):26-30.
    [24]
    祝有海,张永勤,文怀军,等.祁连山冻土区天然气水合物及其基本特征[J].地球学报,2010,31(1):7-16. ZHU Youhai,ZHANG Yongqin,WEN Huaijun,et al.Gas hydrates in the Qilian mountain permafrost and their basic characteristics[J].Acta Geoscientica Sinica,2010,31(1):7-16.
    [25]
    卢振权,祝有海,张永勤,等.青海祁连山冻土区天然气水合物的气体成因研究[J].现代地质,2010,24(3):581-588. LU Zhenquan,ZHU Youhai,ZHANG Yongqin,et al.Study on genesis of gases from gas hydrate in the Qilian Mountain permafrost,Qinghai[J].Geoscience,2010,24(3):581-588.
    [26]
    吴桐,杨涛,徐森,等.轻烃自动定性及解释方法研究与应用[J].录井工程,2010,21(3):19-24. WU Tong,YANG Tao,XU Sen,et al.Study and application of automatic qualitative and interpretation method of light hydrocarbons[J].Mud Logging Engineering,2010,21(3):19-24.
    [27]
    张彩明,唐晓红,王瑞.不同原油轻烃分析方法对比研究[J].化学工程与装备,2008(6):103-108. ZHANG Caiming,TANG Xiaohong,WANG Rui.Contrastive study of the methods for light hydrocarbon in crude oil analysis[J].Chemical Engineering & Equipment,2008(6):103-108.
    [28]
    贺行良,夏宁,刘昌岭,等.FID/TCD并联气相色谱法测定天然气水合物的气体组成[J].分析测试学报,2012,31(2):206-210. HE Xingliang,XIA Ning,LIU Changling,et al.Compositional analysis of gases in natural gas hydrates by GC-FID/TCD[J].Journal of Instrumental Analysis,2012,31(2):206-210.
    [29]
    赵晨曦,梁逸曾,胡黔楠,等.气相色谱保留指数定性方法研究进展[J].分析化学,2005,33(5):715-721. ZHAO Chenxi,LIANG Yizeng,HU Qiannan,et al.Review on gas chromatographic retention index[J].Chinese Journal of Analytical Chemistry,2005,33(5):715-721
    [30]
    胡惕麟,戈葆雄,张义纲,等.源岩吸附烃和天然气轻烃指纹参数的开发和应用[J].石油实验地质,1990,12(4):375-394. HU Tilin,GE Baoxiong,ZHANG Yigang,et al.The development and application of fingerprint parameters for hydrocarbons absorbed by source rocks and light hydrocarbons in natural gas[J].Experimental Petroleum Geology,1990,12(4):375-394.
    [31]
    胡国艺,李剑,李谨,等.判识天然气成因的轻烃指标探讨[J].中国科学(D辑 地球科学),2007, 37(SⅡ):111-117. HU Guoyi,LI Jian,LI Jin,et al.Preliminary study on the origin identification of natural gas by the parameters of light hydrocarbon[J].Science in China (Series D Earth Sciences),2008, 37(SⅠ):131-139.
    [32]
    张敏,李洪波,陈小慧,等.松辽盆地梨树断陷油气生成[M].北京:石油工业出版社,2014. ZHANG Min,LI Hongbo,CHEN Xiaohui,et al.Oil and gas gene-ration of Lishu Fault in Songliao Basin[M].Beijing:Petroleum Industry Press,2014.
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