Advanced Search
Volume 43 Issue 5
Sep.  2021
Turn off MathJax
Article Contents
Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2021  >  43(5): 862-870
HE Chuan, ZHENG Lunju, WANG Qiang, MA Zhongliang, MA Jianfei. Experimental development and application of source rock thermal simulation for hydrocarbon generation and expulsion[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2021, 43(5): 862-870. doi: 10.11781/sysydz202105862
Citation: HE Chuan, ZHENG Lunju, WANG Qiang, MA Zhongliang, MA Jianfei. Experimental development and application of source rock thermal simulation for hydrocarbon generation and expulsion[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2021, 43(5): 862-870. doi: 10.11781/sysydz202105862
shu

Experimental development and application of source rock thermal simulation for hydrocarbon generation and expulsion

doi: 10.11781/sysydz202105862
  • 1.

    SINOPEC Key Laboratory of Petroleum Accumulation Mechanisms, Wuxi, Jiangsu 214126, China

  • 2.

    Wuxi Research Institute of Petroleum Geology, SINOPEC, Wuxi, Jiangsu 214126, China

  • 3.

    State Key Laboratory of Shale Oil and Gas Enrichment and Effective Development, Wuxi, Jiangsu 214126, China

  • Received Date: 2021-05-19
  • Rev Recd Date: 2021-08-21
  • Publish Date: 2021-09-28
    Abstract
  • Simulation experiment was one of the most valuable methods for the study of hydrocarbon generation, expulsion and retention in source rocks. It was summarized in this paper that the progressing status and development significations of thermal simulation experiments. According to the open degree of reaction system, the experimental methods can be classified to three types, including open, closed and restricted systems. Cumulative generation and expulsion of oil and gas at a single temperature step and continuous generation and expulsion of oil and gas in multiple temperature steps were introduced. The main constrains included simulation temperature, pressure, time duration, sample morphology and inorganic reaction medium. The simulation experiments of hydrocarbon generation and expulsion have played an important role in clarifying the processes of oil and gas generation, expulsion and retention and their major controlling factors, establishing oil and gas evolution models of different types of sedimentary organic matter, evaluating the oil and gas resource potential of sedimentary basins, and performing oil and gas source comparison and correlation. The current hydrocarbon generation and expulsion simulation experiments have some limitations, and researches are needed in terms of experimental boundary conditions, physical simulation of hydrocarbon generation and accumulation of source-reservoir synergy, and dynamic calculation of hydrocarbon generation with various constrains.

     

    • FullText(HTML)
  • loading
    • References(40)
  • [1]
    TISSOT B P, WELTE D H. Petroleum formation and occurrence[M]. 2nd ed. Berlin: Springer-Verlag, 1978.
    [2]
    EISMA E, JURG E. Fundamental aspects of the diagenesis of organic matter and the formation of hydrocarbons[C]//Proceedings of 7th World Petroleum Congress. London: World Petroleum Congress, 1967.
    [3]
    黄第藩. 陆相有机质演化和成烃机理[M]. 北京: 石油工业出版社, 1984.

    HUANG Difan. Evolution and hydrocarbon generation mechanism of terrestrial organic matter[M]. Beijing: Petroleum Industry Press, 1984.
    [4]
    张景亷. 论石油的无机成因[M]. 北京: 石油工业出版社, 2001.

    ZHANG Jinglian. On the inorganic origin of petroleum[M]. Beijing: Petroleum Industry Press, 2001.
    [5]
    张林晔, 张守春, 黄开权, 等. 半咸水湖相未熟油成因机理模拟实验研究[J]. 科学通报, 1999, 44(4): 361-367. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB199904005.htm

    ZHANG Linye, ZHANG Shouchun, HUANG Kaiquan, et al. Simulation experiment of immature oil genetic mechanism in lake facies of semi-salt water[J]. Chinese Science Bulletin, 1999, 44(11): 980-988. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB199904005.htm
    [6]
    刘文汇, 王万春. 烃类的有机(生物)与无机(非生物)来源: 油气成因理论思考之二[J]. 矿物岩石地球化学通报, 2000, 19(3): 179-186. https://www.cnki.com.cn/Article/CJFDTOTAL-KYDH200003008.htm

    LIU Wenhui, WANG Wanchun. The organic (biogenic) and inorganic (non-biogenic) sources of hydrocarbons: thought on theory of oil and gas formation[J]. Bulletin of Mineralogy Petrology and Geochemistry, 2000, 19(3): 179-186. https://www.cnki.com.cn/Article/CJFDTOTAL-KYDH200003008.htm
    [7]
    刘全有, 金之钧, 高波, 等. 四川盆地二叠系不同类型烃源岩生烃热模拟实验[J]. 天然气地球科学, 2010, 21(5): 700-704. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201005001.htm

    LIU Quanyou, JIN Zhijun, GAO Bo, et al. Characterization of gas pyrolysates from different types of Permian source rocks in Sichuan Basin[J]. Natural Gas Geoscience, 2010, 21(5): 700-704. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201005001.htm
    [8]
    段毅, 周世新. 塔里木盆地石炭系烃源岩热模拟实验研究: Ⅱ. 生态标志化合物的组成和演化[J]. 石油与天然气地质, 2001, 22(1): 13-16. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT200101002.htm

    DUAN Yi, ZHOU Shixin. Experimental study on thermal simulation of Carboniferous source rocks in Tarim Basin: Ⅱ. Composition and evolution of biomarkers[J]. Petroleum and Natural Gas Geology, 2001, 22(1): 13-16. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT200101002.htm
    [9]
    张有生, 秦勇, 刘焕杰, 等. 沉积有机质二次生烃热模拟实验研究[J]. 地球化学, 2002, 31(3): 273-282. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX200203007.htm

    ZHANG Yousheng, QIN Yong, LIU Huanjie, et al. Investigation on the hydrocarbon regeneration from sedimentary organic matters by pyrolytic simulation[J]. Geochimica, 2002, 31(3): 273-282. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX200203007.htm
    [10]
    米敬奎, 张水昌, 王晓梅. 不同类型生烃模拟实验方法对比与关键技术[J]. 石油实验地质, 2009, 31(4): 409-414. doi: 10.11781/sysydz200904409

    MI Jingkui, ZHANG Shuichang, WANG Xiaomei. Comparison of different hydrocarbon generation simulation approaches and key technique[J]. Petroleum Geology & Experiment, 2009, 31(4): 409-414. doi: 10.11781/sysydz200904409
    [11]
    王治朝, 米敬奎, 李贤庆, 等. 生烃模拟实验方法现状与存在问题[J]. 天然气地球科学, 2009, 20(4): 592-597. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX200904019.htm

    WANG Zhichao, MI Jingkui, LI Xianqing, et al. Current situation and problems of simulation experiment approach of hydrocarbon generation[J]. Natural Gas Geosciences, 2009, 20(4): 592-597. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX200904019.htm
    [12]
    刘宝泉, 蔡冰. 上元古界下马岭组页岩干酪根的油气生成模拟实验[J]. 石油实验地质, 1990, 12(2): 147-161. doi: 10.11781/sysydz199002147

    LIU Baoquan, CAI Bing. A Simulation experiment of petroleum origin on kerogen from shales of the Lower Xiamalin Formation in the Upper Proterozoic[J]. Petroleum Experimental Geology, 1990, 12(2): 147-161. doi: 10.11781/sysydz199002147
    [13]
    王兆云, 程克明, 张柏生, 等. 泥灰岩的生、排烃模拟实验研究[J]. 沉积学报, 1996, 14(1): 127-134. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB601.014.htm

    WANG Zhaoyun, CHENG Keming, ZHANG Baisheng, et al. The study on simulation experiments of hydrocarbon generation and expulsion of mud limestone[J]. Acta Sedimentologica Sinica, 1996, 14(1): 127-134. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB601.014.htm
    [14]
    熊永强, 耿安松, 王云鹏, 等. 干酪根二次生烃动力学模拟实验研究[J]. 中国科学(D辑), 2001, 31(4): 315-320. https://www.cnki.com.cn/Article/CJFDTOTAL-JDXK200104006.htm

    XIONG Yongqiang, GENG Ansong, WANG Yunpeng, et al. Kinetic simulating experiment on the secondary hydrocarbon generation of kerogen[J]. Science in China (Series D: Earth Sciences), 2002, 45(1): 13-20. https://www.cnki.com.cn/Article/CJFDTOTAL-JDXK200104006.htm
    [15]
    MONTHIOUX M, LANDAIS P, MONIN J C. Comparison between natural and artificial maturation series of humic coals from the Mahakam delta, Indonesia[J]. Organic Geochemistry, 1985, 8(4): 275-292.
    [16]
    MONTHIOUX M, LANDAIS P, DURAND B. Comparison between extracts from natural and artificial maturation series of Mahakam delta coals[J]. Organic Geochemistry, 1986, 10(1/3): 299-311.
    [17]
    刘金钟. 桂西北中三叠统板纳组的岩石学及地球化学[D]. 北京: 中国科学院地质与地球物理研究所, 1990.

    LIU Jinzhong. Petrology and geochemistry of the Middle Triassic Banna Formation in northwest Guangxi[D]. Beijing: Institute of Geology and Geophysics, Chinese Academy of Sciences, 1990.
    [18]
    PRICE L C, WENGER L M. The influence of pressure on petroleum generation and maturation as suggested by aqueous pyrolysis[J]. Organic Geochemistry, 1992, 19(1/3): 141-159.
    [19]
    郑伦举, 秦建中, 何生, 等. 地层孔隙热压生排烃模拟实验初步研究[J]. 石油实验地质, 2009, 31(3): 296-302. doi: 10.11781/sysydz200903296

    ZHENG Lunju, QIN Jianzhong, HE Sheng, et al. Preliminary study of formation porosity thermocompression simulation experiment of hydrocarbon generation and expulsion[J]. Petroleum Geology & Experiment, 2009, 31(3): 296-302. doi: 10.11781/sysydz200903296
    [20]
    LOPATIN N V. Temperatura geologicheskoye vema kak factory uglefikatsii (Temperature and geologic time as factors in calcification)[J]. Akademiia nauk SSSR. Izvestiia. Seriia khimicheskaia, 1971, 3, 95-106.
    [21]
    CONNAN J. Time-temperature relation in oil genesis: geologic notes[J]. AAPG Bulletin, 1974, 58(12): 2516-2521.
    [22]
    LANDAIS P, MICHELS R, ELIE M. Are time and temperature the only constraints to the simulation of organic matter maturation?[J]. Organic Geochemistry, 1994, 22(3/5): 617-630.
    [23]
    姜峰, 杜建国, 王万春, 等. 高温超高压模拟实验研究: Ⅱ. 高温高压下烷烃产物的演化特征[J]. 沉积学报, 1998, 16(4): 145-148. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB804.024.htm

    JIANG Feng, DU Jianguo, WANG Wanchun, et al. The study on high pressure high temperature aqueous pyrolysis Ⅱ. Evolutionary characteristics of alkane generated from organic matter under high temperature and high pressure[J]. Acta Sedimentologica Sinica, 1998, 16(4): 145-148. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB804.024.htm
    [24]
    王兆明, 罗晓容, 陈瑞银, 等. 有机质热演化过程中地层压力的作用与影响[J]. 地球科学进展, 2006, 21(1): 39-46. https://www.cnki.com.cn/Article/CJFDTOTAL-DXJZ200601005.htm

    WANG Zhaoming, LUO Xiaorong, CHEN Ruiyin, et al. Effects and influences of pore pressures on organic matter's maturation[J]. Advances in Earth Science, 2006, 21(1): 39-46. https://www.cnki.com.cn/Article/CJFDTOTAL-DXJZ200601005.htm
    [25]
    陈晓东, 王先彬. 压力对有机质成熟和油气生成的影响[J]. 地球科学进展, 1999, 14(1): 31-36. https://www.cnki.com.cn/Article/CJFDTOTAL-DXJZ901.006.htm

    CHEN Xiaodong, WANG Xianbin. Pressure effect on organic matter maturation and petroleum generation[J]. Advance in Earth Sciences, 1999, 14(1): 31-36. https://www.cnki.com.cn/Article/CJFDTOTAL-DXJZ901.006.htm
    [26]
    秦建中, 刘井旺, 刘宝泉, 等. 加温时间、加水量对模拟实验油气产率及地化参数的影响[J]. 石油实验地质, 2002, 24(2): 152-157. doi: 10.11781/sysydz200202152

    QIN Jianzhong, LIU Jingwang, LIU Baoquan, et al. Hydrocarbon yield and geochemical parameters affected by heating time and added water amount in the simulation test[J]. Petroleum Geology & Experiment, 2002, 24(2): 152-157. doi: 10.11781/sysydz200202152
    [27]
    LEWAN M D, WINTERS J C, MCDONALD J H. Generation of oil-like pyrolyzates from organic-rich shales[J]. Science, 1979, 203(4383): 897-899.
    [28]
    王晓锋, 刘文汇, 徐永昌, 等. 水在有机质形成气态烃演化中作用的热模拟实验研究[J]. 自然科学进展, 2006, 16(10): 1275-1281. https://www.cnki.com.cn/Article/CJFDTOTAL-ZKJZ200610011.htm

    WANG Xiaofeng, LIU Wenhui, XU Yongchang, et al. Experimental study on the role of water in the formation and evolution of gaseous hydrocarbons from organic matter[J]. Progress in Natural Science, 2006, 16(10): 1275-1281. https://www.cnki.com.cn/Article/CJFDTOTAL-ZKJZ200610011.htm
    [29]
    王兆云, 程克明, 张柏生. 加水热模拟实验气态产物特征及演化规律研究[J]. 石油勘探与开发, 1995, 22(3): 36-40. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK503.006.htm

    WANG Zhaoyun, CHENG Keming, ZHANG Bosheng. The study on the characteristics and evolution regularity of product of gas under pyrolysis simulation experiments[J]. Petroleum Exploration and Development, 1995, 22(3): 36-40. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK503.006.htm
    [30]
    邹艳荣, 帅燕华, 孔枫, 等. 油气生成过程实验研究的思考与展望[J]. 石油实验地质, 2004, 26(4): 375-382. doi: 10.11781/sysydz200404375

    ZOU Yanrong, SHUAI Yanhua, KONG Feng, et al. Experiments on petroleum generation: considerations and outlook[J]. Petroleum Geology & Experiment, 2004, 26(4): 375-382. doi: 10.11781/sysydz200404375
    [31]
    陈安定, 张文正, 徐永昌. 沉积岩成烃热模拟实验产物的同位素特征及应用[J]. 中国科学(B辑), 1993, 23(2): 209-217. https://www.cnki.com.cn/Article/CJFDTOTAL-JBXK199302014.htm

    CHEN Anding, ZHANG Wenzheng, XU Yongchang. Isotopic characteristics and application of hydrocarbon generation thermal simulation products of sedimentary rocks[J]. Chinese Science(Series B), 1993, 23(2): 209-217. https://www.cnki.com.cn/Article/CJFDTOTAL-JBXK199302014.htm
    [32]
    程克明, 关德师, 陈建平, 等. 烃源岩产烃潜力的热压模拟实验及其在油气勘探中的应用[J]. 石油勘探与开发, 1991(5): 1-11. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK199105002.htm

    CHENG Keming, GUAN Deshi, CHEN Jianping, et al. Laboratory thermal pressure modeling of the hydrocarbon generation potential of source rocks and its application in petroleum exploration[J]. Petroleum Exploration and Development, 1991(5): 1-11. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK199105002.htm
    [33]
    张文正, 裴戈, 关德师. 烃源岩轻烃生成与演化的热压模拟实验研究[J]. 石油勘探与开发, 1991(3): 7-15. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK199103003.htm

    ZHANG Wenzheng, YUAN Ge, GUAN Deshi. Thermal pressure simulation of the formation and evolution of light hydrocarbons of HGSR[J]. Petroleum Exploration and Development, 1991(3): 7-15. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK199103003.htm
    [34]
    祖小京, 妥进才, 张明峰, 等. 矿物在油气形成过程中的作用[J]. 沉积学报, 2007, 25(2): 298-306. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB200702018.htm

    ZU Xiaojing, TUO Jincai, ZHANG Mingfeng, et al. The roles of inorganic minerals on the oil and gas generating processes[J]. Acta Sedimentologica Sinica, 2007, 25(2): 298-306. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB200702018.htm
    [35]
    大庆石油学院. 有机质地化演化模拟实验装置: 87100918[P]. 1988-08-31.

    Daqing Institute of Petroleum. Organic texture evolution simulation test device: CN, 87100918[P]. 1988-08-31.
    [36]
    WANG Qianru, HUANG Haiping, ZHENG Lunjun. Thermal maturity parameters derived from tetra-, penta-substituted naphthalenes and organosulfur compounds in highly mature sediments[J]. Fuel, 2021, 288: 119626.
    [37]
    关德范. 成盆成烃成藏理论思维[M]. 北京: 石油工业出版社, 2004.

    GUAN Defan. Theoretical thinking of basin and hydrocarbon accumulation[M]. Beijing: Petroleum Industry Press, 2004.
    [38]
    MAGOON L B, DOW W. The petroleum system[M]//MAGOON L B, DOW W G. The petroleum system: from source to trap. Tulsa, Okla: American Association of Petroleum Geologists, 1994.
    [39]
    郭旭升, 胡东风, 黄仁春, 等. 四川盆地深层-超深层天然气勘探进展与展望[J]. 天然气工业, 2020, 40(5): 1-14. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG202005002.htm

    GUO Xusheng, HU Dongfeng, HUANG Renchun, et al. Deep and ultra-deep natural gas exploration in the Sichuan Basin: progress and prospect[J]. Natural Gas Industry, 2020, 40(5): 1-14. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG202005002.htm
    [40]
    庞雄奇, 林会喜, 郑定业, 等. 中国深层和超深层碳酸盐岩油气藏形成分布的基本特征与动力机制及发展方向[J]. 地质力学学报, 2020, 26(5): 673-695. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLX202005006.htm

    PANG Xiongqi, LIN Huixi, ZHENG Dingye, et al. Basic characteristics, dynamic mechanism and development direction of deep and ultra-deep carbonate reservoirs in China[J]. Journal of Geomechanics, 2020, 26(5): 673-695. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLX202005006.htm
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(3)  / Tables(1)

    Citation
    XML
    PDF-CN

    Article Metrics

    Article views (819) PDF downloads(177) Cited by()
    Proportional views
    Related

    Website Copyright © Wuxi Research Institute of Petroleum Geology, SINOPEC 苏ICP备15009037号 苏公网安备32021102000780号

    Address：No. 2060, Lihu Avenue, Wuxi, Jiangsu   (214126) Tel：0510-68787204，68787203 Fax：0510-68787113 Email：sysydz.syky@sinopec.com

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return