Advanced Search
Volume 32 Issue 5
. 
Turn off MathJax
Article Contents
Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2010  >  32(5): 513-516
Wang Huitong, Wei Caiyun, Zhang Shuichang, Zhang Dajiang, Wang Hui. THE STUDY ON BIOMARKERS SEPARATION AND ITS CSIA BY MOY MOLECULAR SIEVE[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2010, 32(5): 513-516. doi: 10.11781/sysydz201005513
Citation: Wang Huitong, Wei Caiyun, Zhang Shuichang, Zhang Dajiang, Wang Hui. THE STUDY ON BIOMARKERS SEPARATION AND ITS CSIA BY MOY MOLECULAR SIEVE[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2010, 32(5): 513-516. doi: 10.11781/sysydz201005513
shu

THE STUDY ON BIOMARKERS SEPARATION AND ITS CSIA BY MOY MOLECULAR SIEVE

doi: 10.11781/sysydz201005513
  • 1.

    Petroleum Geology Research and Laboratory Center, Research Institute of Petroleum Exploration and Development, CNPC, Beijing 100083, China

  • 2. The Key Laboratory of Petroleum Geochemistry, CNPC, Beijing 100083, China

  • 3. State Key Laboratory of Enhanced Oil Recovery, Beijing 100083, China

  • Received Date: 2009-03-13
  • Rev Recd Date: 2010-08-11
  • Publish Date: 2010-10-28
    Abstract
  • This paper investigated the column chromatography separation of biomarkers in saturated hydrocarbons by Chinese MOY molecular sieve,the results show that gammarance,steranes and β-carotane can be eluted from the column filled with MOY sieve in which n-alkanes was removed from saturated hydrocarbon.It was demonstrated that gammarance,steranes and β-carotane could be enriched,but hopanes was lost.The results of compound specific isotope analysis(CSIA)shows that there were no compounds isotopic fractionation phenomena occurred during separation.The stable carbon isotope analysis results of gammarance and β-carotane were good,while the stable carbon isotope ana-lysis results of steranes were not ideal due to its relatively high baseline.

     

    • FullText(HTML)
  • loading
    • References(12)
  • [1]
    PETERS K E,WALTERS C C,MOLDOWAN J M.The biomar-ker guide[M].Cambridge:Cambridge University Press,2005.
    [2]
    HAYES J M,F REEMAN K H,POPP B N,et al.Compound-specific isotopic analyses:a novel tool for reconstruction of ancient biogeochemical processes[J].Organic Geochemistry,1990,16(4-6):1115-1128.
    [3]
    SIMONEIT B R T,SCHOELL M.Carbon isotope syste-matics of individual hydrocarbons in hydrothermal petroleums from the Guaymas Basin,Gulf of California[J].Organic Geochemistry,1995,23(9):857-863.
    [4]
    RUBLE T E.,BAKEL A J,PHILP R P.Compound specific isotopic variability in Uinta Basin native bitumens:paleoenvironmental implications[J].Organic Geochemistry,1994,21(6-7):661-671.
    [5]
    SCHOELL M,MCCAFFREY M A,FAGO F J,et al.Carbon isotopic compositions of 28,30-bisno rhopances and other biological markers in a Montarey crude oil[J].Geochemica et Cosmochimica Acta,1992,56(3):1391-1399.
    [6]
    熊永强,耿安松,刘得光.克拉玛依油田稠油中萜类化合物单体碳同位素组成[J].科学通报,1998,43(12):1312-1315.
    [7]
    KENIG F,POPP B N,SUMMONS R E.Preparative HPLC with ultrastable-Y zeolite for compound-specific carbon isotopic analyses[J].Organic Geochemistry,2000,31(11):1087-1094.
    [8]
    MOLDOWAN J M,DAHL J.Combining isotopes with biomarkers and diamondoids:A two-dimensional approach to paleoenvironmental characterization.AAAPG-2004会议论文集[C].北京:[出版者不详],2004:135-137.
    [9]
    董爱正,张林晔,黄第藩,等.饱和烃单体化合物稳定碳同位素测定方法[J].石油勘探与开发,1996,23(2):98-102.
    [10]
    BIDIGARE R R,KENNICUTT M C,KEENEY-KENNICUTT W L,et al.Isolation and purification of chlorophylls a and b for the determination of stable carbon and nitrogen isotope compositions[J].Analytical Chemistry,1991,63(2):130-133.
    [11]
    王汇彤,魏彩云,张水昌,等.国产Y型分子筛对甾烷、藿烷的吸附和脱附研究[J].石油实验地质,2010,32(1),71-75.
    [12]
    高益明.改性MOY 分子筛在降烯烃FCC催化剂中的应用[J].工业催化,2003,11(7):12-16.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Citation
    XML
    PDF-CN

    Article Metrics

    Article views (2305) PDF downloads(916) Cited by()
    Proportional views
    Related

    Website Copyright © Wuxi Research Institute of Petroleum Geology, SINOPEC 苏ICP备15009037号 苏公网安备32021102000780号

    Address：No. 2060, Lihu Avenue, Wuxi, Jiangsu   (214126) Tel：0510-68787204，68787203 Fax：0510-68787113 Email：sysydz.syky@sinopec.com

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return